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Tributylphosphine Oxide CAS 814-29-9

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Tributylphosphine Oxide CAS 814-29-9
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Tributylphosphine Oxide CAS 814-29-9

Synonyms: Tri-n-butylphosphine oxide; Tributylphosphine oxide; Phosphine oxide, tributyl-; n-Butylphosphine oxide; Tri-n-butylphosphine oxide; TBPO; (n-Bu)₃PO; (C₄H₉)₃PO; NSC 102531; Tributylfosfinoxid; Tributylphosphane oxide

Shandong Aure Chemical Co., Ltd. is one of the leading suppliers of TBPO in China and also one of the manufacturers of this product.

We can provide customized requirements in terms of product purity, packaging specifications, and other aspects.

Please contact us to obtain the latest product information.

Product Details

Explore Top-Quality Tributylphosphine Oxide with Aure Chemical

Tributylphosphine Oxide (TBPO) (CAS 814-29-9) is the stable, oxidized form of tributylphosphine. It is a highly versatile reagent, typically supplied as a white to off-white waxy solid or crystalline powder with a mild, characteristic camphor-like odor. TBPO is defined by its strong, polar P=O bond coupled with three lipophilic butyl chains. This unique structure makes it a potent extractant and coordinating agent, widely used in hydrometallurgy for the selective separation and recovery of various metal ions, including rare-earth elements (REEs) and heavy metals. TBPO also finds applications as a catalyst and stabilizing additive in demanding synthetic processes.


Basic Information of TBPO

Meticulously produced and rigorously tested to meet stringent quality standards. We ensure exceptional purity and consistent performance, essential for your critical applications:

CAS No.:814-29-9
EC No.:212-394-3
Linear Formula:C12H27OP
Molecular Weight:218.32
Appearance:White to off-white waxy solid/crystalline powder
Melting Point:64-69 °C(lit.)
Boiling Point:150 °C1.5 mm Hg(lit.)
Density:0.8480
Solubility:Slightly soluble in water; highly soluble in organic solvents, oils, and non-polar media.
Flash Point:150°C
RIDADR:UN 1759 8/PG 2
Chemical Structure:Molecular Structure of Tributylphosphine Oxide

Application Overview

TBPO's high thermal stability and powerful coordinating ability are leveraged across various high-value industrial and synthetic processes:

  • Solvent Extraction (Hydrometallurgy): The primary application is in the liquid-liquid extraction and separation of metal ions, including uranium, plutonium, and crucially, rare-earth elements (REEs), from acid or aqueous leach solutions. The P=O group coordinates strongly with metal cations.

  • Polymerization Catalyst/Additive: Used as a catalyst or co-catalyst in various polymerization reactions, such as the synthesis of polycarbonates and specialized epoxy resins, often influencing reaction kinetics and product properties.

  • Organic Synthesis: Acts as a Lewis base additive or complexing agent to facilitate specific reactions by coordinating to metal centers or other electrophilic species. It is the byproduct in classic reactions like the Mitsunobu and Staudinger reactions.

  • Specialty Materials: Employed as a non-volatile plasticizer or processing aid in polymer systems and coatings, particularly those requiring enhanced thermal stability and non-migratory properties.


Why Choose Aure Chemical for Tributylphosphine Oxide?

Aure Chemical offers TBPO (CAS 814-29-9) with rigorous quality control focused on maximizing its efficacy as a metal extractant and ensuring stability in demanding industrial processes.

  • Ultra-Low Residual Phosphine: Our manufacturing process ensures minimal residual Tributylphosphine (TBP) content (typically<0.05 %). This purity is essential to prevent unwanted side reactions or degradation in sensitive extraction systems and catalytic processes.

  • High Extractant Purity: We provide certified, low-metal TBPO, specifically testing for common trace metal impurities. This guarantees the highest selectivity and efficiency in complex metal separation and rare-earth recovery applications.

  • Controlled Crystalline Form: TBPO is polymorphic. We ensure a consistent crystalline form and morphology with a tightly controlled melting point. This consistency is critical for automated dissolution and dosing systems used in large-scale hydrometallurgical operations.

  • Thermal Stability Verification: Every batch is accompanied by thermal analysis data, verifying its stability up to its decomposition temperature. This provides assurance for customers using TBPO in high-heat industrial mixing or processing environments.


Hazards Classification

  • GHS Classification: Acute Toxicity Oral (GHS07), Acute Toxicity Dermal (GHS07), Acute Toxicity Inhalation (GHS07), Skin Corrosion (GHS05), Serious Eye Damage (GHS05)

  • Hazard Statements: Harmful if swallowed; Harmful in contact with skin; Harmful if inhaled; Causes severe skin burns and eye damage.

  • UN Number: UN 1759

  • Hazard Class: 8 (Corrosive substances)

  • Packing Group: II

GHS05: corrosive pictogram
GHS05: Corrosive
GHS07: exclamation mark pictogram
GHS07: Acute toxicity

Packaging, Transportation & Storage

Aure Chemical ensures that all products are handled in compliance with international safety and quality standards. Each product’s SDS should be consulted for detailed requirements.

Packaging

We use certified UN-rated containers suitable for each chemical type — including steel drums, HDPE drums, IBCs, and ISO tank containers for bulk liquids. All packages are tested for integrity and labeled per IMDG / IATA / ADR standards.

Transportation

Shipments comply with IMDG, IATA, and ADR codes to ensure safe and lawful movement by sea, air, or land. Accompanying documents include SDS, Dangerous Goods Declarations, and COAs.

Storage

Products should be stored in well-ventilated, dry areas, away from heat and incompatible substances. Follow ISO 9001 / 14001 principles for safety, labeling, and periodic inspection.

For detailed handling or customized packaging inquiries, please    contact us.


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