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2-(4-aminophenyl)-5-aminobenzoxazole (APBOA) CAS 13676-47-6

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2-(4-aminophenyl)-5-aminobenzoxazole (APBOA) CAS 13676-47-6

Synonyms: 5-Amino-2-(4-aminophenyl)benzoxazole; 2-(4-Aminophenyl)benzoxazol-5-amine; 2-(4-Aminophenyl)benzo[d]oxazol-5-amine; 5-Benzoxazolamine, 2-(4-aminophenyl)-; 2-(4-Aminophenyl)-1,3-benzoxazol-5-amine; 5-Amino-2-(p-aminophenyl)benzoxazole

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Product Details

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2,2-Bis[4-(4-aminophenoxy)phenyl]-hexafluoropropanane (HFBAPP), CAS 69563-88-8, also known as 4-BDAF, is a fluorinated diamine monomer with flexible ether linkages and a hexafluoropropane core, enabling the synthesis of advanced polymers like polyimides with low dielectric constants, high thermal stability (Tg >420°C, melting points up to 472°C), optical transparency, and solubility.

Basic Information of APBOA

Product Name2-(4-aminophenyl)-5-aminobenzoxazole
Abbreviation

APBOA

CAS Number13676-47-6
Molecular FormulaC13H11N3O
Molecular Weight225.25 g/mol
AppearanceOff-white to tan solid
Purity≥99%
Package1kg/bottle, 20kg/drum, or customized
Molecular formulaAPBOA Molecular Structure

 

Key Properties

  • High thermal stability and structural rigidity

  • Good chemical resistance in harsh environments

  • Stable mechanical properties when incorporated in polymers

  • Can contribute to flame retardancy in derived polymers (polyimide may not require additional flame retardant)

  • Dual amine functionality enables polymer chain extension or crosslinking


Key Applications of APBOA

  • High-Performance Polymers: Used as a monomer for synthesizing polyimides and polyetherimides with excellent thermal and mechanical properties, applied in aerospace composites, aviation materials, and high-temperature environments.

  • Gas Separation Membranes: Incorporated into permeable polyimide membranes for CO₂ capture from the atmosphere and gas transport/separation, leveraging its fluorination for enhanced selectivity and permeability.

  • Electronics and Optoelectronics: Serves as a building block for low-dielectric polyimides in telecommunication devices, flexible substrates for solar cells (achieving power conversion efficiencies up to 16.1%), and capacitors; also used in microelectronics, liquid crystal displays, and laser materials.

  • Energy Storage and Advanced Materials: Utilized in polyetherimides for capacitive energy storage (discharge density of 3.6 J/cm³, efficiency 96.5%); also applied in covalent organic frameworks (COFs), specialty coatings, and nanotechnology.


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